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Eight lacustrine Type I kerogen samples from the Songliao Basin were pyrolyzed using the Rock-Eval equipment, and parallel first-order reaction models including the model with a single frequency factor and a discrete distribution of activation energies (SFF model) and the model with multiple frequency factors and a discrete distribution of activation energies (MFF model) were adopted to analyze kinetic characteristics of hydrocarbon generation of the Type I kerogen samples. The results show that the MFF and SFF models can satisfactory simulate hydrocarbon generation under laboratory conditions and the Type I kerogen shows relatively concentrated activation energy distributions (activation energies of MFF model range from 190 kJ/mol to 250 kJ/mol, activation energies of SFF model range from 220 kJ/mol to 240 kJ/mol), which indicates a homogeneous chemical bond structure of the Type I kerogen. The hydrocarbon generated curves from Type I kerogen were calculated by using the two models with a linear heating rate (3.3 K/Ma). It indicates that the hydrocarbon generation potentials (reaction fractions) are underestimated by using the SFF model during the kerogen thermal degradation for the components with chemical bond of lower and higher activation energies, while this problem can be avoided by using the MFF model. The calculated temperatures for 50% transformation ratio (TR) of all samples differ by as much as 20 °C. For the SFF model, the hydrocarbon generation curve obtained by using the weighted averaged kinetic parameters and the SFF model almost includes every curve calculated by using its own kinetic parameters. While the curve obtained by using the weighted averaged kinetic parameters and the MFF model cannot include every curve for all samples, it lies at the position of the averaged curve of all samples. The application of the MFF model in Songliao Basin shows that if TR 10% is taken as the onset of hydrocarbon generation, the threshold depth of hydrocarbon generation is about 1700 m, which is consistent with other geochemical parameters, such as S1/TOC, S1/(S1 + S2) and HC/TOC. 相似文献
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常规频散曲线反演过程中需要不停地改变分层数、层厚度和层速度等参数,实现过程相对繁琐,而采用细化分层法对反演参数进行简化则避免了上述缺点。具体思路为:根据目的层探测深度(如20m)将地下介质分为若干个(20个)厚度为1m的薄层和1个均匀半空间层(共21层),这样在反演中分层数和层厚度均为已知参量,反演过程只需修改速度参数即可,避免了改变分层数和层厚度等参数,显著简化了反演计算过程。正演计算和反演结果均表明:细化分层与实际分层计算出的频散曲线是等效的,细化分层反演结果的总体效果与真实模型非常接近,这说明细化分层方法用于频散曲线反演是切实可行且有效的;将地下介质划分为1m厚的薄层,反演后每层均可得到1个横波速度,能满足反演分辨率的要求;由于实际地下介质的速度是随深度渐变的,细化分层后比按频散曲线拐点分层(每分层的厚度可能是几米或几十米,同一分层内介质的横波速度相等)更接近实际情况。 相似文献
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在对深部煤田地质钻孔钻进工艺研究的基础上,有针对性选择使用聚合物泥浆,解决了基浆配制用水及泥浆抗地表水水质污染问题。通过改变双管钻具长度和改换取心钻头的切削具,满足软硬互层对钻头钻进效率的影响。在煤系地层钻进中,除采用常规的单管钻具钻进外,在见煤预告下过后,采用加长双管取心钻具,既可保证了回次进尺,又可保证岩心的采取。多项措施落实,不仅解决了生产中的一些难题,收到了较好的效果,而且创造了河北省煤田地质局煤田地质单孔钻探深度2 009.12m的新纪录,为今后深部钻孔的施工积累了经验。 相似文献
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长期动荷载作用下冻结粉土的变形和强度特征 总被引:6,自引:2,他引:4
根据长期动荷载作用下的蠕变试验结果,研究了冻结粉土的变形和动强度特征.试验分3组,第一、二组是小振幅动荷载试验,且第二组的动荷载幅值为第一组的两倍;第三组是大振幅动荷载试验,荷载最小值取接近于零的值,最大值与第一组对应.试验结果表明:各种振幅的动荷载作用下,冻土的累积应变随荷载振动次数的变化规律相同(都包括初始蠕变阶段、稳定蠕变阶段、渐进流阶段)但数值上有差异.在初始和稳定蠕变阶段,第三组试验的累积应变小于第一、二组的,但是第三组试验稳定蠕变阶段的应变速率很大,蠕变曲线迅速进入渐进流阶段,此后其累积应变值大于小振幅动荷载试验的;第一、二组试验的应变幅值随振次的变化规律相似,但与第三组的有明显不同,而且,第三组试验的应变幅值明显大于第一、二组试验的.各种振幅动荷载作用下冻土的残余应变随振次的变化规律相同,且偏移荷载载越大或动荷载振动幅值越大,残余应变越大;冻土的动强度随荷载振动次数的增加而衰减,直至趋于极限动强度,大振幅动荷载试验的极限动强度明显小于小振幅动荷载试验的. 相似文献
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To describe temporal change in tafone development, an S‐shaped curve equation is proposed: Z = Zc [1 ? (n + 1) exp (? β t ) + n exp (? (1 + 1/n) β t )] , where Z is observed tafone depth, Zc is ultimate tafone depth, t is time, and n and β are constants. The applicability of this model is examined using tafone data selected from seven sites, which are categorized into three different salt‐weathering environments: a spray/splash‐dominant (occasionally wave‐affected) supra‐tidal zone, aerosol‐affected coastal regions, and inland desert areas. The results indicate that the equation can well describe tafone development in each of these environments. An investigation based on the values of n and β, determined through a best fit of the equation to the data, suggests that n characterizes site‐specific environmental conditions and β reflects the magnitude of factors controlling the recession mechanism of tafone surfaces. It is found that (1) the maximum rate of tafone growth dramatically decreases from supra‐tidal, through coastal, to desert environments, and (2) the growing mode of tafoni is different depending on the environmental settings. The erosional force to facilitate the development of tafoni at supra‐tidal sites is estimated to be about 400 times greater than that in the general coastal area. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
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